Application of Acidic Ionic Liquid as a Solvent/Catalyst for Preparation of α-Oximinoketones from β-Dicarbonyl Compounds

نویسندگان

  • Ashraf S. Shahvelayati Department of Chemistry,Yadegar-e-Imam Khomeini (RAH), Shahre-rey Branch, Islamic Azad University, Tehran, Iran
  • Fatemeh Sameni Department of Chemistry,Yadegar-e-Imam Khomeini (RAH), Shahre-rey Branch, Islamic Azad University, Tehran, Iran
  • Khadijeh Yadollahzadeh Department of Chemistry, Aliabad Katoul Branch, Islamic Azad University, Aliabad Katoul,Iran
چکیده مقاله:

The selective nitrosation of β-dicarbonyl compounds with sodium nitrite was carried out under1-methyl-3-carboxymethylimidazolium chloride, prepared from N-methylimidazole andchloroacetic acid, as an acidic ionic liquid. The reaction was found to proceed under relativelymild conditions with excellent conversion and selectivity. The ionic liquid was recycled andreused.

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عنوان ژورنال

دوره 11  شماره 4

صفحات  18- 27

تاریخ انتشار 2017-12-01

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